Cation
nutrient balancing is the practice of adjusting the levels of potassium
(K), sodium (Na), calcium (Ca) magnesium (Mg) and hydrogen (H) in the soil to
promote soil, crop and livestock health.
These five elements occur in soil as cations,
or positively charged ions, which are adsorbed (held in plant-available form)
on negatively-charged clay and humus particles. The soil’s ability to hold cations in this way is called the cation exchange capacity, or CEC. Plants roots absorb K, Mg and Ca by
releasing H (acid) in exchange for these essential nutrients. In nature, the soil’s CEC is recharged with
cation nutrients by decomposing leaf litter and droppings, and the gradual
weathering of rocks. Farmers must periodically
replenish K, Mg and Ca by adding organic materials, lime and other mineral
amendments.
There are two ways to manage cation
nutrients. The first is the nutrient sufficiency approach, in which
amendments are added to provide sufficient but non-excessive levels of each
element. This is the strategy that
conscientious farmers use with regard to all
plant nutrients, especially nitrogen (N), phosphorus (P) and K. Soil N and P occur mostly as anions (negatively charged ions), which
are not held on the CEC. Farm nutrient
management plans often focus on preventing N and P excesses that can cause
water pollution. Of the cation
nutrients, plants utilize K in larger quantity than Ca or Mg. Most growers replenish K annually with
manure, compost, hay mulch, or K fertilizers.
Usually, crop residues, existing soil minerals, and lime applied to
correct excessive soil acidity (low pH), provide sufficient Ca and Mg for crop
nutrition. Less frequently, other Ca or
Mg sources may be required on certain soils.
The second strategy is the base saturation ratio approach, which is
applied specifically to the cation nutrients K, Ca and Mg, and the non-nutrient
H (the bearer of soil acidity). Base
saturation ratio is the percentage of the soil’s CEC occupied by each of the
cations. In this system, mineral
amendments are used to adjust the relative
amounts of Ca, Mg and K on the soil's CEC toward a ratio that is thought to
promote good soil tilth and crop nutrition.
During the mid-20th century, soil
scientist William Albrecht developed cation balancing guidelines based on his
research into forage quality and livestock health in the central United States. Since then, others have modified the
"Albrecht formula" for lighter textured soils, which require somewhat
higher Mg and K saturation to ensure sufficient available Mg and K for the
crop. Guidelines for desirable base
saturation ratios are shown below. Note
that Albrecht recommended 10-15% H, which produces a soil pH of about 6.0, as
he considered a mildly acid soil condition more conducive to nutrient
availability than a neutral condition (pH 7.0).
The
Albrecht Formula,
with
adjustments for soil texture class
Light or Medium
or Heavy or
sandy soils loamy soils clay
soils
(CEC <5) (CEC 5-10) (CEC
>10)
------------------------------------------------------------------
%
Ca 60 65-70 68-75
%
Mg 18-20 10-15 10-12
%
K 6-8 3-6 2-5
%
Na <3 <3 <3
%
H 10-15 10-15 10-15
Practitioners of cation balancing
believe that soils with low Ca and too much Mg or K will show poor tilth,
crusting, hardpan formation, poor drainage and aeration. The unbalanced condition is thought to
inhibit beneficial soil organisms, hinder humus formation, reduce availability of
P and other nutrients, and promote soil-borne plant pathogens and noxious
weeds. These conditions can leave the
crop more susceptible to pests and diseases, and yield produce, grains and
forage of lower nutritional quality and shorter shelf life. This cation
imbalance is remedied with applications of high-calcium
limestone if the soil is acid (pH<6.0) or gypsum (calcium sulfate) if pH is higher. Farm testimonials of dramatically improved soil tilth, crop
quality and animal health as a result of these measures can often be found in Acres USA and other sustainable farming
publications.
Critics of the Albrecht formula consider
base saturation ratios irrelevant as long as each individual nutrient is
present in sufficient quantity, and pH is favorable (6.0 to 7.0 for most
crops). Although soil cation balance is
important, there is actually little evidence to suggest that the soil’s base
saturation ratio must be adjusted to the Albrecht formula in order to have
healthy soil, crops and livestock. This
has raised the concern that growers may be spending money, labor and resources
on amendments they do not need, and that will benefit neither the soil nor the
farm’s bottom line.
What do the research findings
suggest? Most crops can thrive under a
fairly wide range of soil Ca and Mg levels, and tilth worsens only at extreme
Mg levels. Soil K levels may be more
critical – it is important to provide enough K but not too much. Finally, cation balancing needs are highly site-specific. Optimum ranges for K, Mg and Ca vary with soil texture, the kinds
of clays present in the soil, organic matter content, soil life, and what crops
are grown. For more details on research results, see the companion information
sheet, Soil Cation Nutrient Balancing in Sustainable Agriculture – missing link
or red herring?
12 Tips on Soil
Cation Nutrient Management
1. CARE FOR THE SOIL AS A LIVING SYSTEM
Feed the soil life with a varied “diet”
of cover crops, organic mulches and other residues to promote a vigorous organic
matter cycle. Use high-quality compost
to inoculate the soil with beneficial organisms. Light applications of one to three tons per acre every one or two
years can accomplish this. A healthy
and diverse web of life in the soil will:
· conserve and recycle
nutrients from organic residues,
· release nutrients in the
root zone of growing crops,
· reduce nutrient leaching
losses,
· slowly unlock nutrients
from insoluble soil minerals,
· stabilize soil pH so that
much less liming is needed.
2. MONITOR TRENDS IN SOIL NUTRIENT LEVELS
Get a soil test every two to three years
so you can observe changes in soil nutrient levels, organic matter and pH over
time. Be sure to use the same lab and the same sampling procedures each time
you re-test, so that successive samples are truly comparable. Note possible
nutrient deficiencies (levels rated “low” or “very low” on the test report) and
excesses (“very high” or “excessive”), and whether or not these nutrient levels
are moving toward a more favorable range (“adequate,” “optimal” or “high” on
test report). However, don’t take the
numbers or the lab’s recommendations too
literally, as some labs prescribe higher fertilizer or lime rates than actually
needed.
For
more information on soil testing see the companion information sheet, How to
Use a Soil Test.
3. IF IT IS NOT BROKEN, DON’T FIX IT
Your soil does not need to conform to
the Albrecht formula to be healthy.
Signs of a healthy soil include:
· rich, brown color (not
black), pleasant earthy odor
· loam and clay soil have
distinctly crumbly appearance
· adequate organic matter
(2-6%, depending on texture)
· pH remains stable at
about 6.0 to 7.0
· soil drains well after a
soaking rain, but remains moist
for several days (sandy) to a
couple of weeks (clay)
· soft, easy-to-work
(except when very dry), no hardpan
· many earthworms and small
insect-like organisms
(may not be evident if soil is dry,
hot or very cold)
· surface residues and
mulch disappear in a few months
· incorporated green manures
disappear in a few weeks
· crops healthy and
resistant to pests, drought, disease
· good yields of high
quality, tasty produce
If your soil seems healthy and is
producing good crops, yet Ca saturation is only 50-60%, and/or Mg is
20-30%, don't worry. You probably do
not need to spend money and time on calcium applications to “correct” the
cation balance.
4. WHEN IN DOUBT, ASK THE PLANT
A foliar nutrient analysis can tell you
whether or not the soil is "in balance" from the plant's point of view.
The lab report will classify each nutrient level as deficient, low,
sufficient, high, or very high (excessive).
This information can tell you whether a low soil Ca level, or high K or
Mg level, might be hurting the crop. On
a biologically active soil, crops may obtain sufficient Ca, P and other
nutrients even if these nutrients are “low” on a soil test.
To help ensure a valid foliar test
result, be sure to follow laboratory
instructions precisely in collecting the sample. Take the sample at the
right stage of growth, take one leaf from each of a sufficient number of
plants, and take leaves from the right part of the plant, are essential for
valid results. You can get sampling
information for each crop from the laboratory.
How to
recognize some cation deficiency and stress disorder symptoms in plants
Potassium deficiency is often described
as a "leaf scorch" on most crops.
It usually starts on recently matured leaves (not the growing
point) with yellow areas between veins which then turn tan or brown. Legumes leaves show a tan speckling. It is most common on acid sandy soils and
heavily cropped soils.
Magnesium deficiency starts with
yellowing between veins on the older leaves, with the whole leaf eventually
becoming yellow. In some cases,
brilliant "fall colors" may develop.
Mg deficiency is likely in vegetables if soil test Mg drops below 60 ppm
or below 8% of CEC, or if the Mg saturation percentage is less than twice that
of K.
Calcium deficiency is less common, and
is harder to detect. It usually affects
the roots first, which show markedly inhibited growth and may turn brown or
rot. Severe deficiency causes the youngest
leaves near the growing point to develop small dead areas, and to become
distorted or cupped. The growing point
itself may die. Ca deficiency is most
likely on soils with very low Ca saturation (25% or less), on sandy soils, and
where soluble K and/or ammonium-N fertilizers, or manure, have been
overapplied.
Calcium stress disorders are localized
Ca deficiencies in the developing fruit, growing point or storage root of
susceptible vegetables. These are much
more common than whole-plant Ca deficiencies.
Examples include:
• tip burn in lettuce and Chinese
cabbage
• internal browning in cabbage and
Brussels sprouts
•
blossom end rot in tomato and pepper
• blackheart in celery
• cavity spot in carrot and parsnip
Ca
stress disorders are caused by an interruption in the flow of Ca from soil
through the plant to the affected part.
Contributing factors include:
• dry soil conditions or alternate
wet/dry cycles
• rapid vegetative growth promoted by
high soluble N
• high temperatures and light levels
• excessive soil K, ammonium-N or soluble salts
•
below-optimal soil Ca levels.
NOTE: crop
nutrient deficiencies can be hard to diagnose correctly. Obtain a foliar nutrient analysis and a soil
test to verify which nutrient(s) need to be supplemented.
5. LIME APPROPRIATELY
It is not necessary to make soils
completely neutral (pH 7.0) through liming.
In fact, most crop nutrients are most available when the soil pH is
about 6.5 (slightly acid). Many crops
can do well anywhere in the pH range of 5.5 (moderately acid) to 7.5 (slightly
alkaline) if the soil life is healthy. In sandy soils, be careful to avoid
overliming, as this can make manganese (Mn) and other essential trace
elements unavailable to crops. Some
liming guidelines:
· on loamy or clayey soils,
lime only when pH drops
below 6.0, apply 2,000 lb/acre
(45 lb/1,000 sq ft).
· on sandy soils, lime only
when pH drops to 5.5 or less,
apply 500 to 1,000 lb/acre (12
to 23 lb/1,000 sq ft).
· lime in conjunction with
organic inputs (green
manure, compost, etc). This helps hold the cation
nutrients.
· small fruit prefer moderately acid soil (pH 5.5 to
6.0)
and rarely need lime. Blueberries like pH 5.0,
and should never be limed.
· use high calcium (calcitic) limestone if the Mg base
is 20% or higher (25% on sandy
soil).
· use dolomitic limestone if Mg base saturation is below
10% (below 15% on sandy soil).
· if the soil’s Mg base
saturation is near optimal, use a
mixture of dolomitic and
calcitic limes, or
alternate types in successive
applications.
· re-test soil the
following season to determine whether
more lime is needed, and if so,
what kind.
Some practical
and economic considerations in liming and gypsum applications
For small scale operations, it is fairly
easy to obtain high calcium lime in 50-lb bags, as the "feed grade
lime" available at many farms stores is high calcium and is suitable for
soil application. For large scale
applications it may be more economical to order a semi-trailer load (22 to 24
tons at $12 per ton plus $2 per mile for delivery, and about $15 per ton for
application) than the bagged product ($120 to 160/ton at the store). Because most lime quarries in our region are
dolomitic, high-Ca lime tends to be more expensive and a little harder to
obtain. Gypsum is even more expensive
at $58 per ton in bulk, or $220 per ton bagged. The added cost may be justified
for high-value crops that are sensitive to Ca level, or on fields with very low
Ca levels.
Although heavy applications (>2000
lb/acre) of finely-pulverized limestone
can be wasteful (a lot of it may leach out), it makes good economic sense to
lime a field just once if possible.
When higher total amounts of lime are indicated (because of a very low
pH, a high CEC, or severe cation imbalance), order a more coarsely ground limestone and apply the full amount in one
operation. The coarser material will be
activated gradually over several years, with minimal leaching losses.
6. CHECK FOR ACID SUBSOIL
Some soils in the southeastern US, have highly acid subsoils, which can be
severely Ca-deficient and overloaded with toxic aluminum (Al). If crops are not thriving despite reasonably
good topsoil pH and nutrient levels, carefully dig down into the subsoil and
observe crop root growth. If roots
suddenly stop at a certain depth and show the browning typical of root Ca
deficiency, get a soil test or at least a pH measurement on soil from the depth
at which roots are inhibited. (Take
samples from several spots and pool them.)
If it is highly acid (pH 5.0 or lower), and/or has extremely low Ca
(less than 30% base saturation), you can supplement subsoil Ca in one of two
ways. If you have the needed equipment,
apply pulverized limestone and chisel-plow or subsoil at least several inches
into the acid layer. Otherwise, apply gypsum at 500 to 1000lb/acre (11-23 lb/1,000 sq ft) to the surface. It will leach down to the acid layer with
rainfall. Several applications every
6-12 months may be needed.
7. WATCH OUT FOR HIGH POTASSIUM
"Enough but not too much" is
the key with this nutrient! Excessive
soil K blocks plant uptake of Ca and Mg, and may contribute to blossom end rot
and other Ca-stress disorders, poor flavor or keeping quality, or other
vegetable production problems. Ample Ca
in plant tissues helps protect the crop against some fungal and bacterial
diseases, but high tissue K levels can cancel
this effect. Soil K base saturation
levels of 8% or more can make some soils more sticky and slower draining. High soil K, with low Mg and Ca can also
lead to grass tetany in cattle, or other livestock health problems.
If soil test K exceeds 350 ppm, or K
base saturation rises above 6% on heavy soils, or 10% on sandy loams:
· cut back on high-K inputs
such as hay mulch, manure,
wood ashes, manure-compost and
NPK fertilizers.
· use cover crops to
maintain soil organic matter and N.
· to build organic matter,
use tree leaves, chipped brush
or straw in mulch or compost. They are lower in K.
· harvest-off excess soil K
with vegetable crops (potato,
sweet potato, brassicas and
winter squash are heavy
K feeders), or alfalfa.
On the other hand, if soil K drops below
100 ppm, or below 5% saturation on a sandy soil, increase use of K-rich
materials such as hay mulch or composted manure.
8. MANAGE SOIL ORGANIC MATTER SUSTAINABLY
It is important to restore soil life and
soil organic matter (SOM) levels on a worn-out soil,. However, once this has been achieved, cut back on organic inputs
from off-farm sources. Tillage accelerates SOM breakdown, and cultivated
soils tend toward “steady state” SOM levels considerably lower than the 10%
often found in virgin temperate forest or prairie. The warmer the climate, the lower the “steady state” SOM level. In the southeastern US, healthy cultivated
soils might have the following organic matter levels:*
· sandy soils and sandy
loams 1.5 to 3%
· loam and silt-loam
soils 2.5
to 5%
· clay-loam and clay
soils 3.5
to 6%
*
Note that these are values for “wet chemistry” methods. If the test lab uses the “loss on ignition”
method, reported SOM values will be about 50% higher.
Intensively managed organic farms
sometimes achieve higher SOM through heavy annual applications of compost,
manure and organic mulch from off-farm sources. However, these farms often have excessive soil P, K and soluble
N, posing a risk of water pollution and soil cation imbalance. If soil tests show ample SOM and “very high”
P and K levels, it is time to cut back on off-farm organic inputs, and use
cover crops to replenish OM and N without adding P and K. This will also save money, labor and
resources.
9. WATCH OUT FOR LOW MAGNESIUM
Crops and livestock may show Mg
deficiency if:
· soil test Mg falls below
60 ppm,
· Mg base saturation is
<8% (15% on sandy soil), or
· Mg base saturation is
less than twice that of K.
To supplement Mg, use dolomitic lime if
the soil is acid (pH<6.0).
Otherwise, apply sul-po-mag at 200-500 lb/acre (4-11 lb/1000 sq ft)
yearly until soil Mg levels are restored.
Caution: if soil K is high, be
sure total K inputs do not exceed K removed by harvest. Use Epsom salts if feasible.
There is considerable evidence that
moderately high Mg levels (20-30% base saturation) will not cause trouble on
most eastern US soils, as long as the Ca base saturation is at least twice that
of Mg.
10. TREAT SOIL TILTH PROBLEMS HOLISTICALLY
If your soil is sticky, hard to work, poorly aerated and drained, or if
a hardpan is present, and the base
saturation ratio differs considerably from the Albrecht guidelines, cation
imbalance may be part of the
problem. Tilth problems respond best to
a combination of measures:
· fracture a hardpan with a
chisel-plow or subsoiler set
just deep enough to penetrate the hard layer.
NOTE: do this when the soil is moderately dry.
· follow subsoiling immediately
with deep-rooted crops.
· minimize heavy-machinery
traffic in the field.
· reduce tillage, and vary
the depth of tillage.
· implement a diverse crop
rotation.
· protect the soil surface
with vegetation, mulch or
residues as much of the season
as possible.
· promote healthy, diverse
soil life by providing diverse
organic materials (cover crops,
mulches, etc.).
· use high quality compost
to inoculate soil with
beneficial organisms (1 to 3
tons/acre will suffice).
· incorporate green manures
and compost into the bio-
logically active surface layer –
the top 3-6 inches.
· apply high-calcium lime
if soil is acid and Ca is below
60% base saturation, or K and/or
Mg are very high.
· apply gypsum at 500
lb/acre (11-23 lb/1,000 sq. ft) on
non-acid loam or clay with Ca
below 60%. Several
annual applications may be
needed to improve tilth.
· on sandy, low-CEC soils,
use gypsum only if Mg or
K is clearly excessive, and only at 300 lb/acre.
Gypsum aggressively leaches K
and Mg from
sandy soils, and can do more
harm than good.
· monitor the soil for
improvements in tilth, and repeat
the soil test to determine if
more Ca may be needed.
11. USE INTEGRATED MANAGEMENT FOR
CALCIUM STRESS DISORDERS
Blossom end
rot, celery blackheart and other Ca-stress disorders are caused by a
combination of factors, only some of which are within the grower's control (see
sidebar on page 2). The soil’s cation
balance may or may not be contributing to the problem. Use the following strategies to combat Ca
stress disorders in vegetable crops:
· adjust planting dates to
avoid temperature extremes.
· keep the root zone evenly
moist through timely
irrigation (drip irrigation
works well).
· avoid excessive soluble N
and K fertilizers.
· if soil K is very high,
reduce K input to bring it down.
· foliar Ca applications
may help.
· if soil Ca is below 65%
base saturation, high calcium
lime or gypsum may help.
Dr. Albrecht suggested the following
economical method for supplying Ca to crops: band or drill finely pulverized
calcitic lime near the crop row at 100-200 lb/acre. This creates a small,
Ca-saturated zone from which the crop can absorb Ca more effectively than if
the same application were diluted across the whole field. You can also use 100
lb/acre of gypsum, which is more soluble.
12. TRY IT OUT ON A SMALL AREA FIRST
If you believe that an unbalanced cation
ratio may be causing production problems but are not sure, try out the calcitic
lime, gypsum or other corrective amendment(s) on a small area before investing
in treatment for the whole farm. Apply
the material to a marked strip through a field. Compare soil tilth, crop production and quality in the strip with
an adjacent “control” strip over a few seasons to see if the cation adjustment
seems to be helping. If you see an improvement in marketable yields or soil
health that would justify the expense and effort, then go ahead!
Mark Schonbeck
NOTE: this information sheet is a "work in
progress." Comments or suggestions
on clarity or accuracy of the information herein, are welcomed by Mark
Schonbeck, 439 Valley Drive NW, Floyd, VA 24091; mschonbeck@usa.net.
Acknowledgements
This work has been made possible by
funding from the Organic Farming Research
Foundation, and from the Southern
Region Sustainable Agriculture Research and Education (SARE) Producer Grants
Program. It is conducted under the
auspices of Virginia Association for
Biological Farming, P.O. Box 1666, Louisa, VA 23093.
I would like to thank Charlie and Miriam
Maloney, Bo Holland, Cathy Guthrie, Chris Rasman, Ron Juftes, Polly Hieser, Joy
Legendre, Ann Shrader, Ellen Polishuk and Hiu Newcomb for their participation
in the field trials, and Margaret Merrill and Steve Diver for their expert
assistance with the literature review.
I am also grateful to Dr. Raymond Weil, Dr. Elaine Ingham and Reid
Putney for their technical advice, assistance and support.